🧪 PREMIUM EXPERIMENTS HANDBOOK

Experiment 25: Preparation and Testing of Oxygen

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Topic:
Gas Preparation
Level:
Ordinary & Higher Level
Exam Focus:
Oxygen Test

1. Experiment Snapshot

FeatureDetails
ApparatusBoiling tube/conical flask, delivery tube, gas jar, water trough, bung, clamp stand.
Chemicals/ReagentsHydrogen peroxide and manganese dioxide catalyst, or potassium chlorate with catalyst depending on method.
Main observationBubbles of oxygen gas are produced; oxygen relights a glowing splint.
Main measurementCollection of oxygen gas and positive gas test.

2. Aim

To prepare oxygen gas in the laboratory and test it using a glowing splint.

3. Quick Theory

Hydrogen peroxide decomposes to form water and oxygen. Manganese dioxide speeds up the reaction as a catalyst.

2H₂O₂ → 2H₂O + O₂
Examiner Tip: Oxygen relights a glowing splint; it does not give a squeaky pop.

4. Apparatus, Chemicals and Safety

CategoryDetails
ApparatusBoiling tube/conical flask, delivery tube, gas jar, water trough, bung, clamp stand.
ChemicalsHydrogen peroxide and manganese dioxide catalyst, or potassium chlorate with catalyst depending on method.
Safety: Wear goggles. Hydrogen peroxide can irritate skin/eyes. Oxygen supports combustion. Keep flames controlled.

5. Labelled Experiment Diagram

Preparation and Testing of Oxygen — Premium Practical Setup
Preparation and Testing of Oxygen Reactants / SampleH₂O₂ + MnO₂ Main Processgas collection Observation / ProductO₂ relights splint Oxygen supports combustion.

6. Procedure

  1. Place hydrogen peroxide in a conical flask.
  2. Add a small amount of manganese dioxide catalyst.
  3. Quickly fit bung and delivery tube.
  4. Collect oxygen over water in an inverted gas jar.
  5. Allow first bubbles to escape if air is present.
  6. Collect a jar of oxygen.
  7. Insert a glowing splint into the gas jar.
  8. Observe the splint relighting.
Examiner Tip: The splint must be glowing, not burning with a flame.

7. Observations and Results

Stage / TestObservationConclusion
Gas productionBubbles formOxygen produced
Glowing splintRelightsOxygen present
CatalystMnO₂ remainsCatalyst not used up
Conclusion: Oxygen can be prepared by decomposition of hydrogen peroxide and identified because it relights a glowing splint.

8. Calculations / Key Chemical Reasoning

The balanced equation shows one mole of oxygen forms from two moles of hydrogen peroxide.

2H₂O₂ → 2H₂O + O₂
Worked Example:
If gas relights a glowing splint, the sample contains oxygen.

9. Sources of Error and Improvements

Source of ErrorEffectImprovement
Gas leaksLess oxygen collectedCheck airtight setup
First gas contains airImpure sampleDiscard first bubbles
Splint too hot/flamingTest unclearUse glowing splint
Too much catalystReaction too vigorousUse small amount
Delivery tube removed lateSuck-back riskRemove before stopping if heated method used

10. Student Common Mistakes

  • Using lighted splint test.
  • Calling the gas hydrogen.
  • Saying catalyst is used up.
  • Forgetting oxygen supports combustion.
  • Not collecting gas over water correctly.

11. Examiner Tips

Tip: Oxygen relights glowing splint.
Tip: MnO₂ is a catalyst.
Tip: Collect over water if gas is not too soluble.
Tip: Keep flames controlled.

12. Examiner Traps

Trap: Glowing splint, not lighted splint.
Trap: Catalyst speeds reaction but is not consumed.
Trap: Oxygen supports combustion but is not itself a fuel.

13. 🎮 Interactive Simulator

Oxygen Gas Test

Choose conditions and test gas.



Observation Window

Gas jar
Choose a condition and run the simulation.

Lab Score: 0/0

14. Past Paper Style Questions

  1. State the aim of this experiment. [2 marks]
  2. Name the main apparatus or reagent used. [2 marks]
  3. Describe the key observation expected. [2 marks]
  4. Give one safety precaution. [1 mark]
  5. Give one source of error and one improvement. [2 marks]
  6. Explain the chemistry behind the result. [3 marks]

15. Mark Scheme Answers

Q1. To prepare and test oxygen gas [2].

Q2. Flask, H₂O₂, MnO₂, delivery tube, gas jar [2].

Q3. Bubbles form and glowing splint relights [2].

Q4. Wear goggles and keep flames controlled [1].

Q5. Gas leak; check airtight apparatus [2].

Q6. Hydrogen peroxide decomposes to water and oxygen, catalysed by MnO₂ [3].

16. Quick Revision Card

Key PointMemory Hook
GasOxygen
Testglowing splint relights
CatalystMnO₂
Equation2H₂O₂ → 2H₂O + O₂
Safetysupports combustion

17. Mastery Checklist