🧪 PREMIUM EXPERIMENTS HANDBOOK

Experiment 13: Preparation of Ethyne

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Topic:
Organic Chemistry
Level:
OL/HL
Exam Focus:
Section A Practical Skills

1. Experiment Snapshot

FeatureDetails
ExperimentPreparation of Ethyne
Difficulty⭐⭐⭐ Practical exam standard
Exam Importance⭐⭐⭐⭐ Organic practicals are common Section A targets
Typical Marks5–15 marks

2. Aim

To prepare ethyne gas from calcium carbide and water, collect it safely, and test for unsaturation.

3. Quick Theory

Calcium carbide reacts with water to produce ethyne gas and calcium hydroxide. Ethyne is an unsaturated hydrocarbon, so it decolourises bromine water.

Examiner Tip: Link the practical step to its purpose. This is where students gain easy explanation marks.

4. Apparatus and Chemicals

ApparatusChemicals
Dropping funnel, conical flask, delivery tube, gas jar, water trough, stopper.Calcium carbide, water, bromine water.
Safety: Wear goggles. Take care with hot apparatus, organic liquids, bromine water, acids, alkalis and flammable substances.

5. Labelled Practical Diagram

Preparation of Ethyne Set up safely apparatus + chemicals Carry out method correct sequence Observe result record conclusion Section A answers must be practical, precise and step-by-step.

6. Step-by-Step Procedure

  1. Place a small amount of calcium carbide in the flask.
  2. Add water slowly using a dropping funnel.
  3. Allow the first gas produced to escape to remove air.
  4. Collect ethyne over water in a gas jar.
  5. Test the gas with bromine water.
  6. Record the colour change.

7. Observations / Results

StageExpected Observation
Gas productionEffervescence / gas bubbles are produced.
Bromine water testOrange/brown bromine water becomes colourless.
ConclusionEthyne is unsaturated.

8. Sources of Error and Improvements

Source of ErrorImprovement
Incorrect heating or poor timing.Heat gently and follow the sequence carefully.
Product loss or contamination.Use clean apparatus and correct collection/filtration technique.
Incorrect observation wording.Use exact exam words such as colourless, precipitate, crystals, reflux, or melting range.

9. Student Common Mistakes

  • Adding water too quickly and making the reaction uncontrolled.
  • Collecting the first gas jar before air is displaced.
  • Forgetting that ethyne is unsaturated.
  • Writing that bromine water turns blue instead of colourless.
  • Confusing ethyne with ethene.

10. Examiner Tips and Traps

Examiner Tip: Organic practicals often ask why a step is done, not just what was done.
Examiner Trap: Do not write vague observations like “changed colour” or “gas formed” without the exact result.

11. 🎮 Interactive Simulator

Try It Yourself

What should be added slowly to calcium carbide?

What is the positive bromine water result?


Result Window

Ready

Score: 0/0

12. Past Paper Style Questions

  1. State the aim of this experiment. [2]
  2. Describe the preparation method in correct order. [4]
  3. State one safety precaution. [2]
  4. State one observation and its conclusion. [3]
  5. State one common source of error and one improvement. [4]

13. Mark Scheme

Aim correct [2].

Method in correct order with key apparatus/chemicals [4].

Safety point suitable for chemicals/heating [2].

Observation and conclusion linked correctly [3].

Valid error and improvement [4].

14. Quick Revision Card

15. Mastery Checklist