🧪 PREMIUM EXPERIMENTS HANDBOOK

Experiment 06: Potassium Permanganate Titration

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Topic:
Volumetric Analysis
Level:
HL
Exam Focus:
Section A Practical Skills

1. Experiment Snapshot

FeatureDetails
ExperimentPotassium Permanganate Titration
Exam Importance⭐⭐⭐⭐ Practical exam standard
Typical Marks5–15 marks

2. Aim

To carry out a potassium permanganate titration and identify the endpoint using its self-indicating colour change.

3. Quick Theory

Potassium permanganate is purple and acts as its own indicator. In acidic solution it is reduced from MnO4- to Mn2+.

Examiner Tip: Always connect the observation or reading to the purpose of the experiment.

4. Apparatus and Chemicals

ApparatusChemicals
Burette, pipette, conical flask, white tile.Potassium permanganate solution, reducing agent and dilute sulfuric acid.
Safety: Wear goggles and follow teacher instructions, especially with acids, alkalis, hot apparatus and oxidising agents.

5. Step-by-Step Procedure

  1. Acidify the reducing agent with dilute sulfuric acid.
  2. Fill the burette with potassium permanganate.
  3. Titrate while swirling.
  4. Stop when a permanent pale pink colour remains.
  5. Repeat for concordant titres.

6. Observations / Results

SituationExpected Result
During titrationPurple colour disappears.
EndpointPermanent pale pink colour.

7. Student Common Mistakes

  • Using hydrochloric acid instead of sulfuric acid.
  • Adding an external indicator.
  • Overshooting the pale pink endpoint.
  • Not acidifying the solution.

8. Examiner Traps

Trap: Students often describe the apparatus but forget the exact observation, reading, or endpoint. Use precise words.

8A. Labelled Diagram

Potassium permanganate is useful because it is self-indicating. The purple colour fades during the reaction, and the endpoint is a very light pink.

Potassium Permanganate Titration
Self-Indicating Endpoint burette purple flask solution endpoint = pale pink
The permanganate colour itself tells you when the titration is finished.
Teacher Voice: Make students say the endpoint out loud as “a permanent pale pink” because that wording earns marks.

9. 🎮 Interactive Simulator

Try It Yourself

Is an external indicator needed?

What is the endpoint?


Result Window

Ready

Score: 0/0

10. Past Paper Style Questions

  1. State the aim of this experiment. [2]
  2. Describe the procedure in order. [4]
  3. State one safety precaution. [2]
  4. State one common error and one improvement. [4]
  5. Explain the key observation/result. [3]

11. Mark Scheme

Aim correct [2].
Procedure in correct order [4].
Safety precaution [2].
Error and improvement [4].
Observation/result explained [3].

12. Mastery Checklist